A characteristic you can’t see or feel can have
subtle or significant effects on life in your lake. It’s called pH, and it’s a measure of how
acid or alkaline your lake’s water is.
We know that water molecules contain two atoms of
hydrogen and one atom of oxygen (H2O). However, some of those
molecules actually exist as positively charged hydrogen ions (H+)
and negatively charged hydroxide ions (OH-).
In pure water, those ions exist in essentially equal
numbers. But when chemicals are added to water, the balance can shift in one
direction or the other. A solution with more hydrogen ions is acidic; a
solution with more hydroxide ions is basic, or alkaline.
pH is measured on a scale from zero (extremely
acidic) to 14 (extremely alkaline). Pure water, which is considered neutral,
has a pH of 7. Relating this to common substances, lemon juice is a fairly
strong acid (pH just over 2), while household ammonia is strongly alkaline (pH
about 12).
Lake waters are not that strongly acidic or
alkaline. Their pH falls generally in a range from about 6 to 8, close to neutral.
Interestingly enough, natural rainwater is fairly acidic (pH about 5.6), and
air pollutants like sulfur dioxide and nitrogen oxides can lower the pH significantly –
causing the harmful phenomenon of acid rain.
Fortunately,
most lakes contain substances that neutralize (or “buffer”) acids, thus keeping
the pH stable. One of the most important of these is calcium carbonate
(limestone).
How
does pH affect life in your lake? That’s complicated, but it determines how
well certain fish species, plants, insects and other life forms survive and
reproduce. For example, at pH below 6.5, walleye spawning is inhibited, and
smallmouth bass disappear below pH 5.5.
pH
can also determine the extent to which certain pollutants are released into the
water from sediments in the lake bottom. For example, a change in pH can cause
more phosphorus to dissolve in water, making it available to feed algae. In
addition, many scientists believe that higher acidity is related to the release
of toxic mercury into lake water. The mercury then can accumulate in fish.
pH
and its effect on lake life is a complex subject. In healthy lakes, the effects
are mostly subtle – pH is just one of many qualities that make each lake
unique.